Ab initio prediction of 29Si-NMR chemical shifts     

Chu Shidong  Li Yingxia  Song Ni  Guan Huashi 《中国海洋大学学报(英文版)》2002,1(1):63-65

The ability of several ab initio models to predict experimental ²⁹Si-NMR chemical shift is examined. The shielding values of trimethylsilyl chloride (A), t-butyldimethylsilyl chloride (B) and allytrimethylsilane (C) are calculated by GIAO, CSGT and IGAIM methods, using HF/6–31G^*, B3LYP/6-31G^*, HF/6–311+G^**, B3LYP/6–311+G^** and MPW1PW91/6–311+G^** models respectively. The ²⁹Si chemical shifts calculated by GIAO method using HF/6–311+G^** model are highly in agreement with those obtained experimentally. All of the models above reproduce the trends of chemical shifts in all cases studied, suggesting that the models are of practical value.  相似文献   

Functional responses for zooplankton feeding on multiple resources: a review of assumptions and biological dynamics     

Wendy Gentleman  Andrew Leising  Bruce Frost  Suzanne Strom  James Murray 《Deep Sea Research Part II: Topical Studies in Oceanography》2003,50(22-26):2847

Modelers often need to quantify the rates at which zooplankton consume a variety of species, size classes and trophic types. Implicit in the equations used to describe the multiple resource functional response (i.e. how nutritional intake varies with resource densities) are assumptions that are not often stated, let alone tested. This is problematic because models are sensitive to the details of these formulations. Here, we enable modelers to make more informed decisions by providing them with a new framework for considering zooplankton feeding on multiple resources. We define a new classification of multiple resource responses that is based on preference, selection and switching, and we develop a set of mathematical diagnostics that elucidate model assumptions. We use these tools to evaluate the assumptions and biological dynamics inherent in published multiple resource responses. These models are shown to simulate different resource preferences, implied single resource responses, changes in intake with changing resource densities, nutritional benefits of generalism, and nutritional costs of selection. Certain formulations are further shown to exhibit anomalous dynamics such as negative switching and sub-optimal feeding. Such varied responses can have vastly different ecological consequences for both zooplankton and their resources; inappropriate choices may incorrectly quantify biologically-mediated fluxes and predict spurious dynamics. We discuss how our classes and diagnostics can help constrain parameters, interpret behaviors, and identify limitations to a formulation's applicability for both regional (e.g. High-Nitrate-Low-Chlorophyll regions comprising large areas of the Pacific) and large-scale applications (e.g. global biogeochemical or climate change models). Strategies for assessing uncertainty and for using the mathematics to guide future experimental investigations are also discussed.  相似文献   

马氏珠母贝生长性状的相关分析   总被引：21，自引：0，他引：21  

何毛贤  史兼华  林岳光  姜卫国  黄良民 《海洋科学》2006,30(11):1-4

对马氏珠母贝(Pinctadamartensi)不同生长时期的壳长、壳高、壳宽和活体质量进行了一年多的跟踪测量。分析表明,在不同生长时期,其4个性状的两两间的相关系数均达到极显著水平(P<0.01),但其相关系数大小排列顺序存在差异,8次测量的平均相关系数大小依次为壳高-壳长>壳宽-体质量>壳高-体质量>壳长-体质量>壳长-壳宽>壳高-壳宽。在不同生长时期,活体质量对壳高、壳宽的偏回归系数均极显著(P<0.01),而对壳长的偏回归系数在第1,3,7,15个月时不显著(P>0.05)。该研究的结果可为珍珠贝的选育种的重要目标性状的确定提供理论指导。  相似文献   

甘肃省摩天岭北坡木本植物叶性状变异及关联   总被引：1，自引：0，他引：1  

李宗杰  田青  宋玲玲 《中国沙漠》2018,38(1):149-156

调查了摩天岭北坡以常绿阔叶林带与落叶阔叶混交林为主的低海拔区(700~1 500m)和针阔叶混交林与亚高山针叶林为主的高海拔区(2 100~3 400m)的21个木本植物群落组成,测定了104种植物的比叶面积(SLA)、叶干物质含量(LDMC)、叶片全磷含量(TPC)、叶片全氮含量(TNC)、叶片全碳含量(TCC)以及叶片厚度(LT)等6个植物功能性状。采用相关性分析对6个植物功能性状的变异和关联进行分析。结果表明:(1)SLA、LT和TCC在高海拔区明显高于低海拔区,而LDMC和TNC表现出高海拔区低于低海拔区;(2)SLA均随海拔的升高表现出降低的趋势,而LDMC和LT都随海拔的升高呈现增加的趋势。低海拔区TCC和高海拔区TCC都随海拔的升高呈增加的趋势;低海拔区TNC和TPC随海拔的变化与高海拔区相反,TNC和TPC在低海拔区随着海拔的升高表现出增加的趋势,而在高海拔区随海拔的增加呈现降低的趋势。(3)在高、低海拔区,SLA与LDMC、LT和TCC均呈极显著的负相关关系(P<0.01),LDMC与LT和TCC呈极显著的正相关关系(P<0.01)。摩天岭北坡不同海拔区木本植物叶片功能性状与海拔的关系,反映了该区域木本植物的不同叶片功能性状对海拔决定的环境异质性的协同响应和适应。  相似文献   

干旱区啤酒花农艺性状与品质的关系     

杨轲  孟亚雄  马小乐  李葆春  司二静  汪军成  任盼荣  王化俊 《中国沙漠》2018,38(4):772-779

明确啤酒花农艺性状与品质的相关性,可以为啤酒花种质资源优选鉴定提供依据。分析了甘肃省河西地区引进的50份啤酒花种质材料单蔓花数、花穗长、花穗粗、单花重、百花重、干鲜比与产量和品质的关系。结果表明：干旱半干旱地区啤酒花种质资源农艺性状和品质指标均存在较大变异,为优异资源的筛选创造了条件。农艺性状和品质指标存在一定相关性,其中,花穗粗和单花重均与干鲜比显著正相关（R²=0.293和R²=0.288）,花穗长和干鲜比与黄腐酚含量呈极显著正相关且干鲜比对黄腐酚含量贡献大于花穗长,而6个主要农艺性状均与α-酸含量无显著相关性。花穗长、花穗粗可以作为干鲜比大、产量和黄腐酚含量高、药用价值好的啤酒花种质资源筛选的农艺性状指标,但高α-酸含量的啤酒花种质资源无法通过农艺性状去筛选。  相似文献   

Rare species, habitat diversity and functional redundancy in marine benthos   总被引：1，自引：0，他引：1  

Kari E. Ellingsen  Judi E. Hewitt  Simon F. Thrush 《Journal of Sea Research》2007,58(4):291-301

Macro-ecological theories relating species richness, abundance, range size, biological traits and environmental tolerance have rarely been tested in marine soft-sediments, despite the spatial extent of these habitats and the inherent richness of resident communities. This study examines the contribution of rare species to marine soft-sediment communities from New Zealand, focussing on the relationships of range size with abundance, environment, habitat diversity and life history traits. 54% of the 351 species sampled exhibited restricted ranges (found at ≤ 2 sites). In contrast to many terrestrial systems, we observed only a weak positive relationship between abundance and frequency of occurrence. Restricted-range species were not randomly distributed, with their distribution related to habitat characteristics, suggesting an important link between habitat diversity and rarity. They exhibited a similar range of traits to the total observed species pool, suggesting that they are not only important to biodiversity but could play a role in stability. Restricted range species were generally not small and this, together with the number of different biological traits represented, suggests that rare species are important to the functioning of marine systems. Thus, our results highlight the importance of considering rare species in habitat-based approaches to conservation.  相似文献   

Functional analysis of landscape connectivity at the landscape,component, and patch levels: A case study of Minqing County,Fuzhou City,China     

《Applied geography (Sevenoaks, England)》2017

Maintaining forest landscape connectivity is one of the most effective ways to alleviate natural forest fragmentation and biodiversity loss problems. Recently, graph theory based metrics have been used as powerful tools in the assessment of landscape connectivity. However, the functional features of landscape units at different structure levels, based on which outcomes can be enriched and advice can be given for practical applications, have been overlooked. In this study, a series of graph-based connectivity indices was calculated to 1) evaluate the optimal threshold distance, 2) identify the key landscape units at the component and patch levels, and 3) classify the functional types of components and patches and analyze functional patterns at different structural levels. The relationship between patch size and patch functional performance in maintaining landscape connectivity was discussed. With a natural forest area in Minqing County of China as the study area, recommendations regarding forest conservation and connectivity enhancement were provided based on the research conclusions. This study provides a way to comprehensively analyze habitat fragmentation and functional patterns for local forest conservation.  相似文献   

小黄鱼(Pseudosciaena polyactis)形态性状与体质量的相关性及通径分析   总被引：4，自引：0，他引：4  

刘峰  陈琳  楼宝  詹炜  陈睿毅  徐冬冬  王立改  徐麒翔  马涛  毛国民 《海洋与湖沼》2016,47(3):655-662

为了研究野生小黄鱼(Pseudosciaena polyactis)繁殖后代的形态性状对体质量的影响作用,以随机采集的729尾4.5月龄小黄鱼为研究对象,对每尾个体的体质量(g)和8个形态性状(cm):全长(X1)、体长(X2)、头长(X3)、躯干长(X4)、尾部长(X5)、尾柄长(X6)、尾柄高(X7)和体高(X8)进行准确测定,运用相关分析、多元回归分析和通径分析方法,分别计算性状间的相关系数、构建形态性状与体质量的多元回归方程,获得了通径系数和决定系数,进行了养殖小黄鱼的形态性状对体质量的影响研究。结果显示,8个形态性状与体质量的相关系数均达到极显著水平(P0.01);通径分析中,4个形态性状对体质量的通径系数达到极显著水平(P0.01),它们是影响体质量的重要指标,其中体长(通径系数:0.589)对体质量的直接影响最大。应用逐步多元回归分析建立了以体质量为因变量(Y),体长(X2)、躯干长(X4)、尾柄高(X7)和体高(X8)为自变量的回归方程:Y=–32.377+3.064X2–1.511X4+14.285X7+4.438X8。模型等式中形态性状与体质量的相关指数R2=0.927,说明所选性状是影响体质量的主要形态性状。以上分析结果为小黄鱼的选育测量指标的确定提供了理论依据。  相似文献   

日本囊对虾(Marsupenaeus japonicus)秋繁仔虾形态表型与抗流性能间的相关性   总被引：1，自引：1，他引：0       下载免费PDF全文

王志铮  朱海军  任夙艺  斯烈钢  祝本强 《海洋与湖沼》2016,47(2):360-368

于水温(18.0±1.0)°C、盐度20、pH 8.1±0.2条件下,以水流为胁迫因子(时长1min),以日本囊对虾秋繁同生群仔虾[总长(7.643±0.639)mm]为实验对象,以溢水口(实验初始时刻仔虾放置处)为起点,按等距离间距法将自制的水流测定装置(总长1m)依次划分为A(0—25cm)、B(25—50cm)、C(50—75cm)、D(75—100cm)和E(100cm)等五个区段,在确认实验终了时刻分布于A区段内仔虾数量占实验仔虾总数5%的水流速度为0.823cm/s后,以此为实验流速,借助显微扫描像素测量技术和多元分析方法定量研究了A、B、C、D、E实验群体(依次为实验终止时刻分布于A、B、C、D、E区段内的仔虾)个体间形态比例性状间的差异。结果表明:(1)在所涉15项形态测量指标中,各实验群体间均无显著差异(P0.05)的形态性状共计8项,依次为X_4(眼径)、X_5(头胸甲长)、X_6(头胸甲高)、X_7(第一腹节长)、X_8(第二腹节长)、X_9(第三腹节长)、X_~(10)(第四腹节长)和X_14(腹节高);(2)在所涉17项形态比例指标中,实验群体间均无显著差异(P0.05)的形态比例性状共计7项,依次为C_2(额剑长/总长)、C_9(第五腹节长/总长)、C_(10)(尾节长/总长)、C_(11)(尾扇长/总长)、C_(15)(头胸甲高/头胸甲长)、C_(16)(腹节高/第一腹节长)和C_(17)(尾节高/尾节长);(3)经主成分分析,提取到的5个特征值均大于1的主成分,累计贡献率达80.795%,其中第1主成分39.561%,其载荷绝对值大于0.5的主要影响变量占形态比例性状总数的47.059%;(4)将A实验群体定义为水流胁迫处理选留群,B、C、D、E实验群体统归为水流胁迫处理淘汰群。采用逐步判别法,以判别贡献率较大的C_1(第一触角柄长/总长)、C3(眼径/总长)、C7(第三腹节长/总长)、C13(额剑长/头胸甲长)为自变量,所建的Fisher分类函数方程组可较清晰地区分淘汰群和选留群个体,其中选留群的判别准确率P_1、P_2分别为98%和84.85%,淘汰群的判别准确率P_1、P_2分别为82.25%和97.63%,两者综合判别准确率为90.12%。综上可知,借助形态表型分型可实现日本囊对虾仔虾不同抗流性能群体间的筛选。  相似文献   

文蛤早期发育阶段生长性状遗传参数的估计     

梁冰冰  王鸿霞 《海洋科学》2016,40(3):47-52

采用部分因子设计构建了23个全同胞家系,应用单性状及两性状动物模型对文蛤(Meretrix meretrix)早期不同生长发育时期的生长性状进行遗传力和相关性估计。结果表明,文蛤附着变态期以及稚贝期生长性状的遗传力并无显著差别,在0.11~0.41范围内变化,属于中等遗传力。非遗传的共同环境效应随着年龄的增长而呈现上升趋势,由附着变态期的0.02逐渐增加到稚贝期的0.38,且稚贝期的共同环境效应显著大于其附着变态期(P0.01)。壳长与壳高表型相关和遗传相关的分析结果显示,从附着变态期到稚贝期,壳长与壳高之间的表型相关及遗传相关都存在极显著的正相关性,相关系数的范围分别为0.84~0.95、0.93~0.99。早期发育连续时间段生长性状之间的遗传相关均为正相关,但并不显著,且不同时期的遗传相关也不尽相同(0.34~0.71)。  相似文献